Nicole will be taking on the role of a high-powered CEO in upcoming film Babygirl and she was business chic in a flowing black dress that really captured the imagination – we just can't wait for her premiere look later on Friday.
Meanwhile, Cate Blanchett continued to bring looks following a dotty suit and sleek silver dress, with the actress this time rocking an awe-inspiring white dress with a beautiful sheer section.
See more of our favorite stars below…
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Nicole Kidman
Nicole looked so glam on Friday with her stylish black Bottega Venneta number. The outfit highlighted the star's statuesque physique and her glam earrings were the cherry on top as she made her first appearance of the day.
2/16
Nicole Kidman
Nicole later wore a gorgeous Schiaparelli gown at the red carpet.
3/16
Cate Blanchett
Cate has been owning the red carpet since the festival's first day and at the premiere of her new series, Disclaimer, she ruled the roost once again. The A-lister looked beautiful in a stunning white Louis Vuitton outfit that even carried a daring sheer section.
4/16
Eva Green
Eva was an enchanting vixen on the red carpet, styling out an eye-catching black dress that was seeped in Gothic undertones.
5/16
Lili Reinhart
Riverdale's Lili Reinhart might have had one of our favorite looks for the night, styling out a sublime Armani midnight-black dress covered in jewels.
6/16
Camila Mendes
Camila Mendes looked miles away from her iconic Riverdale character in this beautiful sparking gown by Armani.
7/16
Kaya Scodelario
Skins actress Kaya Scodelario also rocked Armani, in a gorgeous shimmering one-shouldered gown.
8/16
Antonio Banderas
We can't wait to see Antonio in upcoming thriller Babygirl, and the star looked cool as he rocked a smart-casual look with a captivating shirt and white trousers at the photocall.
9/16
Ella Purnell
Ella Purnell rocked a gorgeous vintage-inspired Armani gown with ruched detailing and a diamond-encrusted neckline.
10/16
Sacha Baron Cohen
Borat star Sacha Baron Cohen also seemed to be inspired by a super suave spy, rocking a complete Thom Sweeney outfit, for the premiere of new series Disclaimer.
11/16
Camille Cottin
Glamorous French actress and Killing Eve star Camille Cottin looked amazing in her latest fashion win, a stylish black suit-dress.
12/16
Louis Partridge
English actor Louis Partridge looked to be channelling his inner James Bond as he showed up to the premiere of the final episodes of Disclaimer in a suave suit that wouldn't look out of place on 007.
13/16
Ncuti Gatwa
The 15th Doctor managed to land the TARDIS at Venice! Ncuti stepped out in an all-black Armani look with Messika jewellery that wouldn't be out of place in the Time Lord's wardrobe.
14/16
Sophie Wilde
Sophie is starring alongside Nicole in Babygirl, and she channeled a villainous look for the red carpet with a ravishing black dress and sheer face covering.
15/16
Harris Dickinson
Harris will be appearing opposite Nicole in Babygirl as her younger lover, and the actor wore a tan shirt and black trousers for his photocall appearance.
16/16
Charli Howard
Glam model Charli drove us wild as she made a grand entrance in a polka-dot dress. Divine!
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